Germanium analogs of carbenium ions


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The review summarizes advances in the production of germanium analogs of carbenium ions both per se in solutions and crystals and as intermediates in reactions of organogermanium compounds. The data on the structures of germylium cations of different types are considered. Emphasis is given to the reactivity of germylium ions and their ion-molecule reactions with nucleophilic reagents in the gas and condensed phases.

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T. Kochina

I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences; Department of Chemistry, St. Petersburg State University

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Email: t-kochina@mail.ru
俄罗斯联邦, 2 nab. Makarova, St. Petersburg, 199034; 26 Universitetsky prosp., Petrodvorets, St. Petersburg, 198504

D. Myalochkin

Department of Chemistry, St. Petersburg State University

Email: t-kochina@mail.ru
俄罗斯联邦, 26 Universitetsky prosp., Petrodvorets, St. Petersburg, 198504

V. Avrorin

Department of Chemistry, St. Petersburg State University

Email: t-kochina@mail.ru
俄罗斯联邦, 26 Universitetsky prosp., Petrodvorets, St. Petersburg, 198504

E. Sinotova

Department of Chemistry, St. Petersburg State University

Email: t-kochina@mail.ru
俄罗斯联邦, 26 Universitetsky prosp., Petrodvorets, St. Petersburg, 198504

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