Email this article Germanium analogs of carbenium ions
- Authors: Kochina T.A.1,2, Myalochkin D.L.2, Avrorin V.V.2, Sinotova E.N.2
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Affiliations:
- I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
- Department of Chemistry, St. Petersburg State University
- Issue: Vol 65, No 3 (2016)
- Pages: 597-620
- Section: Reviews
- URL: https://journal-vniispk.ru/1066-5285/article/view/237412
- DOI: https://doi.org/10.1007/s11172-016-1345-8
- ID: 237412
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Abstract
The review summarizes advances in the production of germanium analogs of carbenium ions both per se in solutions and crystals and as intermediates in reactions of organogermanium compounds. The data on the structures of germylium cations of different types are considered. Emphasis is given to the reactivity of germylium ions and their ion-molecule reactions with nucleophilic reagents in the gas and condensed phases.
About the authors
T. A. Kochina
I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences; Department of Chemistry, St. Petersburg State University
Author for correspondence.
Email: t-kochina@mail.ru
Russian Federation, 2 nab. Makarova, St. Petersburg, 199034; 26 Universitetsky prosp., Petrodvorets, St. Petersburg, 198504
D. L. Myalochkin
Department of Chemistry, St. Petersburg State University
Email: t-kochina@mail.ru
Russian Federation, 26 Universitetsky prosp., Petrodvorets, St. Petersburg, 198504
V. V. Avrorin
Department of Chemistry, St. Petersburg State University
Email: t-kochina@mail.ru
Russian Federation, 26 Universitetsky prosp., Petrodvorets, St. Petersburg, 198504
E. N. Sinotova
Department of Chemistry, St. Petersburg State University
Email: t-kochina@mail.ru
Russian Federation, 26 Universitetsky prosp., Petrodvorets, St. Petersburg, 198504
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