Influence of aging of poly[(trimethylsilyl)prop-1-yne] on the thermodynamics of sorption of light hydrocarbons

V. E. Shiryaeva; A. A. Korolev; T. P. Popova; A. Yu. Kanat´eva; A. A. Kurganov

doi:10.1007/s11172-018-2216-2

Influence of aging of poly[(trimethylsilyl)prop-1-yne] on the thermodynamics of sorption of light hydrocarbons

作者: Shiryaeva V.E.¹, Korolev A.A.¹, Popova T.P.¹, Kanat´eva A.Y.¹, Kurganov A.A.¹
隶属关系:
1. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
期: 卷 67, 编号 7 (2018)
页面: 1307-1311
栏目: Article
URL: https://journal-vniispk.ru/1066-5285/article/view/242747
DOI: https://doi.org/10.1007/s11172-018-2216-2
ID: 242747

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详细

Changes in the properties of the poly[(trimethylsilyl)prop-1-yne] (PTMSP) film deposited on the walls of a quartz capillary under the action of high temperatures were studied by chromatographic methods. The change in the thermodynamic parameters of sorption of light hydrocarbons related to both physical aging of the PTMSP film and, possibly, its chemical destruction was examined.