Semicoking of Kansko-Achinsk lignite and applications of tar fractions

Аннотация

The semicoking of regular lignite from the Berezovsk field in Kansko-Achinsk Basin (moisture content 1.6–19.6 wt %) at 450–550°C in a reactor with solid heat carrier is studied. The products are semicoke (up to 68.1%), tar (up to 9.5%), gas (up to 31.9%), and pyrogenetic water. The composition of the semicoking gas is quantitatively determined. Its main components are hydrogen (up to 71.7%) and methane (up to 17.2%). The heat of combustion of the semicoking gas is 12.39–16.25 MJ/m³. The yield of phenolic fractions in the semicoking tar, consisting of phenol and its alkyl derivatives with one or two short substituents (C₁–C₃), is 10.5–14.6%. After hydraulic purification of the gasoline fraction in the semicoking tar (below 180°C), gasoline with octane rating 75.8 (by the motor method) is obtained. It consists of aromatic, saturated, and unsaturated hydrocarbons (C₅–C₈). The diesel fuel derived from tar fractions distilled off at temperatures up to 350°C are of good quality, except for their low cetane rating. The high-boiling tar fractions may be used to produce lignite pitch and pitch coke. The semicoke obtained is a very effective reducing agent in the production of phosphorus. It may also be used as a lean additive in coking batch and as a component in enriched domestic coal briquets.