Отправить статью по E-mail Molecular Complex of Cadmium(II) Trifluoroacetate with Triphenylphosphine: Crystal Structure and Luminescence Properties
- Авторы: Kokunov Y.V.1, Kovalev V.V.1, Gorbunova Y.E.1, Churakov A.V.1, Kozyukhin S.1
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Выпуск: Том 45, № 7 (2019)
- Страницы: 473-477
- Раздел: Article
- URL: https://journal-vniispk.ru/1070-3284/article/view/214758
- DOI: https://doi.org/10.1134/S1070328419070042
- ID: 214758
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Аннотация
Cadmium compound [Cd(CF3COO)2(Ph3P)2] is synthesized, and its crystal structure is determined. The crystals are monoclinic: space group C2/c, a = 20.318(4), b = 10.432(2), c = 18.661(4) Å, β = 104.18(1)°, V = 3834.8(13) Å3, Z = 4, ρcalcd = 1.495 g/cm3. The Cd atom arranged on the 2-fold crystallographic axis has a distorted octahedral coordination due to four oxygen atoms of crystallographically equivalent trifluoroacetate ligands and two phosphorus atoms of triphenylphosphine. Each fluorine atom of the trifluoroacetate groups is randomly disordered over three equally probable positions. The compound is luminescent.
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Об авторах
Yu. Kokunov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: kovavlad@igic.ras.ru
Россия, Moscow, 119991
V. Kovalev
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: kovavlad@igic.ras.ru
Россия, Moscow, 119991
Yu. Gorbunova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: kovavlad@igic.ras.ru
Россия, Moscow, 119991
A. Churakov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: kovavlad@igic.ras.ru
Россия, Moscow, 119991
S. A. Kozyukhin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: kovavlad@igic.ras.ru
Россия, Moscow, 119991
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