The effect of functional substitution on thermal stability of pyridinylporphyrins under argon atmosphere


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The data on thermal stability under argon atmosphere of a series of porphyrin ligands containing meso- and β-positioned electron-donor (Me, Et, or Ph) groups as well as electron-acceptor pyridinyl substituents differing in the heteroatom location are presented. Thermogravimetric analysis and electron absorption spectroscopy studies have shown that pyridinylporphyrins are thermally stable at heating to 360–500°С depending on the functional substitution in the molecule.

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N. Berezina

Ivanovo State University of Chemistry and Technology

编辑信件的主要联系方式.
Email: sky_berezina@rambler.ru
俄罗斯联邦, Sheremetevskii pr. 7, Ivanovo, 153000

Do Minh

Ivanovo State University of Chemistry and Technology

Email: sky_berezina@rambler.ru
俄罗斯联邦, Sheremetevskii pr. 7, Ivanovo, 153000

Yu. Tikhonova

Ivanovo State University of Chemistry and Technology

Email: sky_berezina@rambler.ru
俄罗斯联邦, Sheremetevskii pr. 7, Ivanovo, 153000

N. Tumanova

Ivanovo State University of Chemistry and Technology

Email: sky_berezina@rambler.ru
俄罗斯联邦, Sheremetevskii pr. 7, Ivanovo, 153000

S. Guseinov

G.A. Krestov Institute of Solutions Chemistry

Email: sky_berezina@rambler.ru
俄罗斯联邦, Ivanovo

M. Bazanov

Ivanovo State University of Chemistry and Technology

Email: sky_berezina@rambler.ru
俄罗斯联邦, Sheremetevskii pr. 7, Ivanovo, 153000

M. Berezin

G.A. Krestov Institute of Solutions Chemistry

Email: sky_berezina@rambler.ru
俄罗斯联邦, Ivanovo

A. Glazunov

Ivanovo State University of Chemistry and Technology

Email: sky_berezina@rambler.ru
俄罗斯联邦, Sheremetevskii pr. 7, Ivanovo, 153000

A. Semeikin

Ivanovo State University of Chemistry and Technology

Email: sky_berezina@rambler.ru
俄罗斯联邦, Sheremetevskii pr. 7, Ivanovo, 153000

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