DP-sensors based on MF-4SC membrane and silica with hydrophobic surface for determination of phenylalanine, valine, and methionine cations


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Abstract

The influence of modification of MF-4SC membranes with silica (or surface-hydrophobized silica) nanoparticles on their ionic conductivity and diffusion permeability as well as the response stability and sensitivity of the membrane-based DP-sensors for cations of amino acids containing hydrophobic fragment has been studied. The membranes modified with surface-hydrophobized silica exhibited the 2–5 times reduced relative error of determination of the hydrophobic amino acids as compared to the initial membranes.

About the authors

A. V. Parshina

Voronezh State University

Author for correspondence.
Email: parshina_ann@mail.ru
Russian Federation, Universitetskaya pl. 1, Voronezh, 394006

E. Yu. Safronova

Kurnakov Institute of General and Inorganic Chemistry

Email: parshina_ann@mail.ru
Russian Federation, Moscow

T. S. Titova

Voronezh State University

Email: parshina_ann@mail.ru
Russian Federation, Universitetskaya pl. 1, Voronezh, 394006

O. V. Bobreshova

Voronezh State University

Email: parshina_ann@mail.ru
Russian Federation, Universitetskaya pl. 1, Voronezh, 394006

I. A. Prikhno

Kurnakov Institute of General and Inorganic Chemistry

Email: parshina_ann@mail.ru
Russian Federation, Moscow

A. B. Yaroslavtsev

Kurnakov Institute of General and Inorganic Chemistry

Email: parshina_ann@mail.ru
Russian Federation, Moscow

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