Email this article Synthesis of azamacrocyclic compounds by cyclocondensation of aliphatic α,ω-diamines with acetone
- Authors: Anisimova N.A.1, Khristoforova E.I.1, Trishin Y.G.1
-
Affiliations:
- St. Petersburg State University of Industrial Technology and Design
- Issue: Vol 86, No 9 (2016)
- Pages: 2047-2051
- Section: Article
- URL: https://journal-vniispk.ru/1070-3632/article/view/216129
- DOI: https://doi.org/10.1134/S1070363216090115
- ID: 216129
Cite item
Open Access
Access granted
Subscription Access
Abstract
Cyclocondensation of 1,4-diaminobutane and 1,6-diaminohexane with acetone afforded the corresponding 18- and 22-membered trans-azamacrocyclic Curtis compounds in high yield, which contain two azomethine and amine nitrogen atoms. A complex mixture of the products formed containing less than 25% of 16-membered azamacrocyclic cis- and trans-isomers when reacting 1,3-diaminopropane with acetone.
About the authors
N. A. Anisimova
St. Petersburg State University of Industrial Technology and Design
Email: trish@YT4470.spb.edu
Russian Federation, ul. I. Chernykh 4, St. Petersburg, 198095
E. I. Khristoforova
St. Petersburg State University of Industrial Technology and Design
Email: trish@YT4470.spb.edu
Russian Federation, ul. I. Chernykh 4, St. Petersburg, 198095
Yu. G. Trishin
St. Petersburg State University of Industrial Technology and Design
Author for correspondence.
Email: trish@YT4470.spb.edu
Russian Federation, ul. I. Chernykh 4, St. Petersburg, 198095
Supplementary files
