Synthesis and structure of gold complexes [Ph3P(4-FC6H4CH2)]+[AuCl4] and [Ph3PCH2CH=CHMe]+[AuCl4]


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Abstract

The reaction of tetrachloroauric acid hexahydrate with (4-fluorobenzyl)triphenylphosphonium and (buten-2-yl)triphenylphosphonium (1:1, mol) chlorides results in the formation of the [Ph3P(4-FC6H4CH2)]+ [AuCl4] and [Ph3PCH2CH=CHMe]+[AuCl4] complexes. Structure of the complexes was studied by the X-ray diffraction (XRD) analysis.

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V. V. Sharutin

National Research South Ural State University

Author for correspondence.
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080

O. K. Sharutina

National Research South Ural State University

Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080

V. S. Senchurin

National Research South Ural State University

Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080

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