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Thermochemical study of the trans- and cis-isomeric forms of 4-(4-methoxystyryl)pyridine N-oxide

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Abstract

The trans and cis form of 4-(4-methoxystyryl)pyridine N-oxide were studied. The spectral characteristics of cis-4-(4-methoxystyryl)pyridine N-oxide were determined in acetonitrile. The melting and thermal decomposition processes of the trans and cisforms of 4-(4-methoxystyryl)pyridine N-oxide were studied by thermochemical methods. It was establish that the thermal decomposition of 4-(4-methoxystyryl)pyridine N-oxide begins with the cleavage of the bond between the pyridine and benzene rings.

About the authors

Yu. A. Gubarev

Krestov Institute of Solution Chemistry

Author for correspondence.
Email: gua@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040

S. N. Golubev

Krestov Institute of Solution Chemistry

Email: gua@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040

N. Sh. Lebedeva

Krestov Institute of Solution Chemistry

Email: gua@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040

A. I. V’yugin

Krestov Institute of Solution Chemistry

Email: gua@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040

V. P. Andreev

Petrozavodsk State University

Email: gua@isc-ras.ru
Russian Federation, Petrozavodsk, Kareliya

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