On the possibility of homolytic addition of  N -bromohexamethyldisilazane to the triple carbon–carbon bond

V. I. Rakhlin; I. P. Tsyrendorzhieva; A. I. Albanov

doi:10.1134/S1070363217040351

On the possibility of homolytic addition of N-bromohexamethyldisilazane to the triple carbon–carbon bond

Authors: Rakhlin V.I.¹, Tsyrendorzhieva I.P.¹, Albanov A.I.¹
Affiliations:
1. A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Issue: Vol 87, No 4 (2017)
Pages: 880-881
Section: Letters to the Editor
URL: https://journal-vniispk.ru/1070-3632/article/view/219599
DOI: https://doi.org/10.1134/S1070363217040351
ID: 219599

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Abstract

By an example of a reaction of N-bromohexamethyldisilazane with phenylacetylene the possibility of its homolytic addition to the triple carbon-carbon bond with the formation of a mixture of the corresponding E- and Z-isomers in the ratio of 1.2 : 1 was shown.