Effect of ferrocene on the synthesis of graft copolymers of vinylpolysiloxane and styrene

E. A. Masloborodova; E. V. Kaganova; N. S. Gusakova; L. V. Agibalova; E. Yu. Maretina; I. V. Baranets; R. M. Islamova

doi:10.1134/S1070363217050243

Effect of ferrocene on the synthesis of graft copolymers of vinylpolysiloxane and styrene

Authors: Masloborodova E.A.¹, Kaganova E.V.¹, Gusakova N.S.¹, Agibalova L.V.¹, Maretina E.Y.¹, Baranets I.V.¹, Islamova R.M.²
Affiliations:
1. Lebedev Research Institute of Synthetic Rubber
2. St. Petersburg State University
Issue: Vol 87, No 5 (2017)
Pages: 1038-1046
Section: Article
URL: https://journal-vniispk.ru/1070-3632/article/view/219896
DOI: https://doi.org/10.1134/S1070363217050243
ID: 219896

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Abstract

The effect of ferrocene on the synthesis of graft poly(dimethylsiloxanes) by radical copolymerization of a polysiloxane containing terminal trivinylsiloxy groups with styrene. The backbone in the synthesized graft copolymers is formed by a linear poly(dimethylsiloxane) with a part of its vinyl groups involved in grafting polystyrene chains. The products were studied by gel permeation chromatography, ¹Н NMR spectroscopy, and optical microscopy.