Synthesis of new ferrocene derivatives with a 4,5-dichloroisothiazole fragment


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详细

Conjugates of ferrocene and 4,5-dichloroisothiazole were synthesized, where the ferrocene and isothiazole moieties are linked through various structural fragments. The acylation of ferrocene with 4,5- dichloroisothiazole-3-carbonyl chloride gave (4,5-dichloroisothiazol-3-yl) ferrocenyl ketone; the acylation of aminomethylferrocene furnished the corresponding amide. The esterification of ferrocene-1,1′-dicarboxylic acid with 4,5-dichloroisothiazol-3-yl-methanol resulted in the formation of the corresponding ester. The condensation of 1,1′-diacetylferrocene with 4,5-dichloroisothiazole-3-carbaldehyde afforded ferrocenophane containing 4,5-dichloroisothiazole moieties.

作者简介

A. Kletskov

Institute of Physical Organic Chemistry

编辑信件的主要联系方式.
Email: avkletskov@gmail.com
白俄罗斯, ul. Surganova 13, Minsk, 220072

I. Kolesnik

Institute of Physical Organic Chemistry

Email: avkletskov@gmail.com
白俄罗斯, ul. Surganova 13, Minsk, 220072

E. Dikusar

Institute of Physical Organic Chemistry

Email: avkletskov@gmail.com
白俄罗斯, ul. Surganova 13, Minsk, 220072

N. Zhukovskaya

Institute of Physical Organic Chemistry

Email: avkletskov@gmail.com
白俄罗斯, ul. Surganova 13, Minsk, 220072

V. Potkin

Institute of Physical Organic Chemistry

Email: avkletskov@gmail.com
白俄罗斯, ul. Surganova 13, Minsk, 220072

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