Addition of Diphenylphosphine to Two Molecules of 1,4-Naphthoquinone


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Abstract

According to NMR data, diphenylphosphine reacted with two equivalents of 1,4-naphthoquinone under mild conditions to form betaine, 1',4'-dihydroxynaphth-2'-yl-diphenylphosphonium (1-hydroxynaphth-2-yl-4-ate), which was converted to bis(1,4-dihydroxynaphth-2-yl)diphenylphosphonium salts when treated with hydrogen bromide or trifluoracetic acid.

About the authors

N. R. Khasyatullina

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Author for correspondence.
Email: nadya.ksu@mail.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

A. M. Vazykhova

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: nadya.ksu@mail.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

V. F. Mironov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: nadya.ksu@mail.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

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