S,S-Complexes of Copper(I) Halides with 1,2-Bis(3,5-dimethyloxazol-4-ylmethylsulfanyl)ethane as New Catalysts for Phenylacetylene Aminomethylation

V. R. Akhmetova; N. S. Akhmadiev; G. M. Nurtdinova; V. M. Yanybin; A. B. Glazyrin; A. G. Ibragimov

doi:10.1134/S1070363218070113

S,S-Complexes of Copper(I) Halides with 1,2-Bis(3,5-dimethyloxazol-4-ylmethylsulfanyl)ethane as New Catalysts for Phenylacetylene Aminomethylation

Authors: Akhmetova V.R.¹, Akhmadiev N.S.¹, Nurtdinova G.M.², Yanybin V.M.¹, Glazyrin A.B.³, Ibragimov A.G.¹
Affiliations:
1. Institute of Petrochemistry and Catalysis, Ufa State Research Center
2. Ufa State Petroleum Technological University
3. Bashkir State University
Issue: Vol 88, No 7 (2018)
Pages: 1418-1424
Section: Article
URL: https://journal-vniispk.ru/1070-3632/article/view/222313
DOI: https://doi.org/10.1134/S1070363218070113
ID: 222313

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Abstract

New metal–heterocycle S,S-complexes based on Cu(I) binary halides and a polydentate ligand, 1,2- bis(3,5-dimethyloxazol-4-ylmethylsulfanyl)ethane have been prepared. The obtained complexes have demonstrated high catalytic activity in aminomethylation of phenylacetylene with N,N,N',N'-tetramethylmethanediamine, bis(oxazolidin-3-yl)methane, or benzaldehyde–piperidine system.