Reaction of 3,4,6-Triisopropyl- о -benzoquinone with 3,4,6-Triisopropylcatechol

Yu. A. Kurskii; A. S. Shavyrin; T. I. Kulikova; V. A. Kuropatov; G. A. Abakumov

doi:10.1134/S1070363218080054

Reaction of 3,4,6-Triisopropyl-о-benzoquinone with 3,4,6-Triisopropylcatechol

Authors: Kurskii Y.A.¹, Shavyrin A.S.¹, Kulikova T.I.¹, Kuropatov V.A.¹, Abakumov G.A.¹
Affiliations:
1. G.A. Razuvaev Institute of Organometallic Chemistry
Issue: Vol 88, No 8 (2018)
Pages: 1584-1589
Section: Article
URL: https://journal-vniispk.ru/1070-3632/article/view/222351
DOI: https://doi.org/10.1134/S1070363218080054
ID: 222351

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Abstract

Formation of protonated 3,4,6-triisopropylsemiquinone radicals in solution of a mixture of 3,4,6- triisopropyl-о-benzoquinone and 3,4,6-triisopropylcatechol was shown using ESR spectroscopy. Heating the mixture to 110°С leads to the formation of the condensation products, additional amount of 3,4,6-triisopropylcatechol, and evolution of propylene. Mathematical simulation of the kinetics of the reaction was performed.