Electrophilic Catalysis in the Synthesis of Aryl Methyl- and Phenylphosphonochloridates


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Abstract

The reaction of methyl- and phenylphosphonic dichlorides with phenols in the presence of anhydrous magnesium chloride as catalyst or magnesium metal as precatalyst provides a simple, efficient, and practical method of synthesis of the corresponding aryl methyl- and phenylphosphonochloridates.

About the authors

E. I. Goryunov

Nesmeyanov Institute of Organoelement Compounds

Author for correspondence.
Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991

I. B. Goryunova

Nesmeyanov Institute of Organoelement Compounds

Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991

G. N. Molchanova

Nesmeyanov Institute of Organoelement Compounds

Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991

I. Yu. Kudryavtsev

Nesmeyanov Institute of Organoelement Compounds

Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991

T. V. Baulina

Nesmeyanov Institute of Organoelement Compounds

Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991

A. A. Khodak

Nesmeyanov Institute of Organoelement Compounds

Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991

T. V. Strelkova

Nesmeyanov Institute of Organoelement Compounds

Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991

V. K. Brel

Nesmeyanov Institute of Organoelement Compounds

Email: gor.evg@rambler.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991

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