Email this article (Iodomethyl)fluorosilanes: Synthesis and Reactions
- Authors: Gostevskii B.А.1, Lazareva N.F.1
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Affiliations:
- A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Issue: Vol 88, No 10 (2018)
- Pages: 2084-2088
- Section: Article
- URL: https://journal-vniispk.ru/1070-3632/article/view/222471
- DOI: https://doi.org/10.1134/S1070363218100092
- ID: 222471
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Abstract
The methods of synthesis of bifunctional (iodomethyl)fluorosilanes of general formula ICH2SiMenF3–n (n = 0, 2) have been elaborated; the structure was proved by 1H, 13C, 29Si NMR spectroscopy. The reaction of (iodomethyl)dimethylfluorosilane with O-trimethylsilyl derivative of N,N'-dimethylhydrazide of trifluoroacetic acid gives rise to the formation of 2,2,4,4-tetramethyl-6-(trifluoromethyl)-3,4-dihydro-2Н-1,4,5,2-oxadiasilin-4-ium iodide with tetracoordinate silicone atom.
About the authors
B. А. Gostevskii
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: nataliya.lazareva@gmail.com
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
N. F. Lazareva
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Author for correspondence.
Email: nataliya.lazareva@gmail.com
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
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