Synthesis of a 16-Membered P4N2 Macrocycle with Pyridyl-Substituted Phosphorus Atoms


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Abstract

The first example of 16-membered aminomethylphosphines with pyridyl substituents on the phosphorus atom was synthesized as an RSSR isomer by covalent self-assembly in the system 1,3-bis[(pyridin-2-yl)phosphino]propane–formaldehyde–isopropylamine.

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T. I. Wittmann

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Author for correspondence.
Email: FesenkoTI@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

E. I. Musina

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: FesenkoTI@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

I. A. Litvinov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: FesenkoTI@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

A. A. Karasik

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: FesenkoTI@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

O. G. Sinyashin

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: FesenkoTI@yandex.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

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