Synthesis and properties of functionalized alkylalkoxysilanes

A. V. Lebedev; R. M. Minas’yan; A. M. Abramkin; V. D. Sheludyakov; N. E. Kuzmina; A. B. Lebedeva; G. E. Surikov; V. B. Rybakov

doi:10.1134/S1070363216080144

Synthesis and properties of functionalized alkylalkoxysilanes

Autores: Lebedev A.V.¹, Minas’yan R.M.¹, Abramkin A.M.¹, Sheludyakov V.D.¹, Kuzmina N.E.¹, Lebedeva A.B.¹, Surikov G.E.¹, Rybakov V.B.²
Afiliações:
1. State Research Institute of Chemistry and Technology of Organoelement Compounds
2. Lomonosov Moscow State University
Edição: Volume 86, Nº 8 (2016)
Páginas: 1859-1863
Seção: Article
URL: https://journal-vniispk.ru/1070-3632/article/view/215942
DOI: https://doi.org/10.1134/S1070363216080144
ID: 215942

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A method of chloroalkylalkoxysilanes synthesis scalable to pilot production has been proposed. Morpholinotrialkoxysilanes have been prepared and studied as vulcanizing agents for low-molecular silicone rubbers. The reaction of N-morpholinomethyltrialkoxysilanes with triethanolamine has afforded N-[(silatranyl)-methyl]morpholine; it has been studied by X-ray analysis.