Thermal behavior of polymers prepared using the tri- n -butylboron– p -quinone system

D. V. Ludin; A. V. Markin; S. D. Zaitsev; S. E. Shuvalov; Yu. L. Kuznetsova

doi:10.1134/S1070427216060124

Thermal behavior of polymers prepared using the tri-n-butylboron–p-quinone system

Authors: Ludin D.V.¹, Markin A.V.¹, Zaitsev S.D.¹, Shuvalov S.E.¹, Kuznetsova Y.L.¹
Affiliations:
1. Lobachevsky State University of Nizhny Novgorod
Issue: Vol 89, No 6 (2016)
Pages: 921-925
Section: Macromolecular Compounds and Polymeric Materials
URL: https://journal-vniispk.ru/1070-4272/article/view/213959
DOI: https://doi.org/10.1134/S1070427216060124
ID: 213959

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Abstract

Thermal behavior of polymers [poly(methyl methacrylate), poly(methyl acrylate), polystyrene] prepared in the presence of tri-n-butylboron and a series of p-quinones was studied. The heat resistance of the polymers increases with an increase in the inhibition constant of the p-quinone taken for the synthesis. The enhancement of the heat resistance of the polymer is due to a decrease in the amount of weak bonds and to the formation of associates.