Email this article Electrochemical conversion of aqueous ethanol solution in an electrolyzer with a solid polymer electrolyte
- Authors: Pushkareva I.V.1,2, Pushkarev A.S.1,2, Grigoriev S.A.1, Lyutikova E.K.2, Akel’kina S.V.2, Osina M.A.1, Slavcheva E.P.3, Fateev V.N.2
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Affiliations:
- National Research University “Moscow Power Engineering Institute,”
- National Research Centre “Kurchatov Institute,”
- Acad. Evgeni Budevski Institute of Electrochemistry and Energy Systems
- Issue: Vol 89, No 12 (2016)
- Pages: 2109-2111
- Section: Brief Communications
- URL: https://journal-vniispk.ru/1070-4272/article/view/214623
- DOI: https://doi.org/10.1134/S1070427216120260
- ID: 214623
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Abstract
The electrochemical conversion of an aqueous ethanol solution (40 vol %) in an electrolysis cell with a solid polymer electrolyte in the presence of various electrocatalysts (Pt, Ir, Ir0.3Ru0.3Sn0.4O2, and Pt0.5Ru0.5) was studied. The electrocatalytic conversion of the ethanol solution at low current densities (up to 0.3 A cm−2) is characterized by a significant (by up to 50%) decrease in the cell voltage relative to water electrolysis. Possible diffusion of ethanol from the anode zone to the cathode zone will not significantly affect operation of the platinum electrocatalyst.
About the authors
I. V. Pushkareva
National Research University “Moscow Power Engineering Institute,”; National Research Centre “Kurchatov Institute,”
Email: sergey.grigoriev@outlook.com
Russian Federation, ul. Krasnokazarmennaya 14, Moscow, 111250; pl. Kurchatova 1, Moscow, 123182
A. S. Pushkarev
National Research University “Moscow Power Engineering Institute,”; National Research Centre “Kurchatov Institute,”
Email: sergey.grigoriev@outlook.com
Russian Federation, ul. Krasnokazarmennaya 14, Moscow, 111250; pl. Kurchatova 1, Moscow, 123182
S. A. Grigoriev
National Research University “Moscow Power Engineering Institute,”
Author for correspondence.
Email: sergey.grigoriev@outlook.com
Russian Federation, ul. Krasnokazarmennaya 14, Moscow, 111250
E. K. Lyutikova
National Research Centre “Kurchatov Institute,”
Email: sergey.grigoriev@outlook.com
Russian Federation, pl. Kurchatova 1, Moscow, 123182
S. V. Akel’kina
National Research Centre “Kurchatov Institute,”
Email: sergey.grigoriev@outlook.com
Russian Federation, pl. Kurchatova 1, Moscow, 123182
M. A. Osina
National Research University “Moscow Power Engineering Institute,”
Email: sergey.grigoriev@outlook.com
Russian Federation, ul. Krasnokazarmennaya 14, Moscow, 111250
E. P. Slavcheva
Acad. Evgeni Budevski Institute of Electrochemistry and Energy Systems
Email: sergey.grigoriev@outlook.com
Bulgaria, Acad. Georgi Bonchev str. 10, Sofia, 1113
V. N. Fateev
National Research Centre “Kurchatov Institute,”
Email: sergey.grigoriev@outlook.com
Russian Federation, pl. Kurchatova 1, Moscow, 123182
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