New sorbents based on organosilicon guanidine derivatives


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Abstract

Monomeric and polymeric organosilicon derivatives of 1-acetylguanidine, which exhibits sorption properties, were synthesized. The organosilicon polymers prepared were studied as sorbents for heavy [Hg(II)] and noble [Ag(I), Au(III), Rh(III), Pd(II), Pt(IV)] metals. They actively take up platinum group metals and exhibit metallochromic properties by analogy with the starting compound, 1-acetylguanidine. Their interaction with all the elements studied is accompanied by coloration. The initial monomers exhibit similar metallochromic properties.

About the authors

E. N. Oborina

Favorskii Institute of Chemistry, Siberian Branch; Irkutsk Scientific Center, Siberian Branch

Author for correspondence.
Email: summer2006.06@mail.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033; ul. Lermonotova 134, Irkutsk, 664033

S. N. Adamovich

Favorskii Institute of Chemistry, Siberian Branch; Irkutsk Scientific Center, Siberian Branch

Email: summer2006.06@mail.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033; ul. Lermonotova 134, Irkutsk, 664033

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