Specific Features of N-Morpholinoethyl Methacrylate Synthesis
- Authors: Leshina M.N.1, Ladilova N.Y.1, Malysheva A.A.1, Makarova I.Y.1, Shirshin K.V.1
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Affiliations:
- Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant
- Issue: Vol 91, No 7 (2018)
- Pages: 1118-1122
- Section: Organic Synthesis and Industrial Organic Chemistry
- URL: https://journal-vniispk.ru/1070-4272/article/view/215943
- DOI: https://doi.org/10.1134/S107042721807008X
- ID: 215943
Cite item
Abstract
Methods for synthesis of N-morpholinoethyl methacrylate were compared. It was shown that the monomer produced by acylation of N-morpholinoethanol with methacrylic acid anhydride or methacryloyl chloride spontaneously polymerizes in storage. The possible reasons for the spontaneous polymerization of N-morpholinoethyl methacrylate produced by the acylation method were considered. The conditions in which a stable-in-storage monomer can be obtained in 86–88% yield by the method of re-esterification of methyl methacrylate with N-morpholinoethanol were determined.
About the authors
M. N. Leshina
Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant
Author for correspondence.
Email: leshina@nicp.ru
Russian Federation, Dzerzhinsk, Nizhny Novgorod oblast, 606000
N. Yu. Ladilova
Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant
Email: leshina@nicp.ru
Russian Federation, Dzerzhinsk, Nizhny Novgorod oblast, 606000
A. A. Malysheva
Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant
Email: leshina@nicp.ru
Russian Federation, Dzerzhinsk, Nizhny Novgorod oblast, 606000
I. Yu. Makarova
Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant
Email: leshina@nicp.ru
Russian Federation, Dzerzhinsk, Nizhny Novgorod oblast, 606000
K. V. Shirshin
Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant
Email: leshina@nicp.ru
Russian Federation, Dzerzhinsk, Nizhny Novgorod oblast, 606000
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