Specific Features of N-Morpholinoethyl Methacrylate Synthesis


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Abstract

Methods for synthesis of N-morpholinoethyl methacrylate were compared. It was shown that the monomer produced by acylation of N-morpholinoethanol with methacrylic acid anhydride or methacryloyl chloride spontaneously polymerizes in storage. The possible reasons for the spontaneous polymerization of N-morpholinoethyl methacrylate produced by the acylation method were considered. The conditions in which a stable-in-storage monomer can be obtained in 86–88% yield by the method of re-esterification of methyl methacrylate with N-morpholinoethanol were determined.

About the authors

M. N. Leshina

Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant

Author for correspondence.
Email: leshina@nicp.ru
Russian Federation, Dzerzhinsk, Nizhny Novgorod oblast, 606000

N. Yu. Ladilova

Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant

Email: leshina@nicp.ru
Russian Federation, Dzerzhinsk, Nizhny Novgorod oblast, 606000

A. A. Malysheva

Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant

Email: leshina@nicp.ru
Russian Federation, Dzerzhinsk, Nizhny Novgorod oblast, 606000

I. Yu. Makarova

Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant

Email: leshina@nicp.ru
Russian Federation, Dzerzhinsk, Nizhny Novgorod oblast, 606000

K. V. Shirshin

Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant

Email: leshina@nicp.ru
Russian Federation, Dzerzhinsk, Nizhny Novgorod oblast, 606000

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