Oxidative Transformations of Ethane and Ethylene on VMoTeNbO Catalysts


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Abstract

Comparative studies of oxidative transformations of ethane and ethylene were performed on multi-component oxide catalysts of the preset cationic composition, V0.3Mo1Te0.23Nb0.12, differing in the final calcination temperature. The highest (∼74%) ethylene yield in oxidative dehydrogenation of ethane is reached on the catalysts calcined in the temperature interval 550–650°C, which is due to the formation of the maximal amount of the active M1 phase.

About the authors

V. M. Bondareva

Boreskov Institute of Catalysis, Siberian Branch

Author for correspondence.
Email: valent@catalysis.ru
Russian Federation, Novosibirsk, 630090

E. V. Lazareva

Boreskov Institute of Catalysis, Siberian Branch

Email: valent@catalysis.ru
Russian Federation, Novosibirsk, 630090

T. Yu. Kardash

Boreskov Institute of Catalysis, Siberian Branch; Novosibirsk State University

Email: valent@catalysis.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090

V. I. Sobolev

Boreskov Institute of Catalysis, Siberian Branch

Email: valent@catalysis.ru
Russian Federation, Novosibirsk, 630090

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