Synthesis and properties of 2,3,9,10,16,17,23,24-octakis(3-phenoxyphenoxy)phthalocyanine and its complexes with erbium of diverse structures
- Authors: Koptyaev A.I.1, Ageeva E.S.1, Galanin N.E.1, Shaposhnikov G.P.1
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Affiliations:
- Research Institute of Macroheterocyclic Compounds at Ivanovo State University of Chemical Engineering
- Issue: Vol 52, No 2 (2016)
- Pages: 261-267
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/213774
- DOI: https://doi.org/10.1134/S1070428016020172
- ID: 213774
Cite item
Abstract
Reaction of 4,5-dichlorophthalonitrile with 3-phenoxyphenol led to the formation of 4,5-bis(3-phenoxyphenoxy)phthalonitrile. It has underlain the synthesis of 2,3,9,10,16,17,23,24-octakis(3-phenoxy-phenoxy) phthalocyanine and its single and double deck sandwich complexes with erbium. As show the electron absorption spectra the complexes are dissociated in dichloromethane at concentrations below 1 × 10–5 mol L–1.
About the authors
A. I. Koptyaev
Research Institute of Macroheterocyclic Compounds at Ivanovo State University of Chemical Engineering
Email: nik-galanin@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000
E. S. Ageeva
Research Institute of Macroheterocyclic Compounds at Ivanovo State University of Chemical Engineering
Email: nik-galanin@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000
N. E. Galanin
Research Institute of Macroheterocyclic Compounds at Ivanovo State University of Chemical Engineering
Author for correspondence.
Email: nik-galanin@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000
G. P. Shaposhnikov
Research Institute of Macroheterocyclic Compounds at Ivanovo State University of Chemical Engineering
Email: nik-galanin@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000
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