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Synthesis and properties of 2,3,9,10,16,17,23,24-octakis(3-phenoxyphenoxy)phthalocyanine and its complexes with erbium of diverse structures


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Abstract

Reaction of 4,5-dichlorophthalonitrile with 3-phenoxyphenol led to the formation of 4,5-bis(3-phenoxyphenoxy)phthalonitrile. It has underlain the synthesis of 2,3,9,10,16,17,23,24-octakis(3-phenoxy-phenoxy) phthalocyanine and its single and double deck sandwich complexes with erbium. As show the electron absorption spectra the complexes are dissociated in dichloromethane at concentrations below 1 × 10–5 mol L–1.

About the authors

A. I. Koptyaev

Research Institute of Macroheterocyclic Compounds at Ivanovo State University of Chemical Engineering

Email: nik-galanin@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000

E. S. Ageeva

Research Institute of Macroheterocyclic Compounds at Ivanovo State University of Chemical Engineering

Email: nik-galanin@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000

N. E. Galanin

Research Institute of Macroheterocyclic Compounds at Ivanovo State University of Chemical Engineering

Author for correspondence.
Email: nik-galanin@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000

G. P. Shaposhnikov

Research Institute of Macroheterocyclic Compounds at Ivanovo State University of Chemical Engineering

Email: nik-galanin@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000

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