Synthesis of (–)-(3aR,4R,5S,6aS)-4-[(acetoxy)methyl]-1-oxohexahydro-1H-cyclopenta[c]furan-5-yl Acetate


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Abstract

A new 1,2,3,4-functionalized cyclopentane, (–)-(3aR,4R,5S,6aS)-4-[(acetoxy)methyl]-1-oxohexahydro-1H-cyclopenta[c]furan-5-yl acetate, has been synthesized by cleavage of a tricyclic bowl-shaped aminal, (2aR,3S,4aS,6bR)-3-hydroxy-6-[(1R)-1-phenylethyl]-octahydro-5H-1-oxa-6-azacyclopenta[cd]pentalen-5-one.

About the authors

A. M. Gimazetdinov

Institute of Chemistry

Author for correspondence.
Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

V. V. Loza

Institute of Chemistry

Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

A. Z. Al’mukhametov

Institute of Chemistry

Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

M. S. Miftakhov

Institute of Chemistry

Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

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