Reaction of 2-{[2-(ethenyloxy)ethoxy]methyl}oxirane with oxazolidin-2-ones


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Abstract

Reactions of 2-{[2-(ethenyloxy)ethoxy]methyl}oxirane with N-unsubstituted oxazolidin-2-ones give mixtures of isomeric 3-{3-[2-(ethenyloxy)ethoxy]-2-hydroxypropyl}- and 5-{[2-(ethenyloxy)ethoxy]- methyl}-3-(2-hydroxyalkyl)oxazolidin-2-ones. If the initial oxazolidin-2-one contains two alkyl groups on C4, 3-{3-[2-(ethenyloxy)ethoxy]-2-hydroxypropyl}oxazolidin-2-ones are selectively formed.

About the authors

N. A. Lobanova

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Author for correspondence.
Email: lona@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

E. Kh. Sadykov

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: lona@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

V. K. Stankevich

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: lona@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

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