Oxidation with CrO 3 ·2Py of levoglucosenone and 1,3-dienes Diels-Alder adducts

I. M. Biktagirov; L. Kh. Faizullina; Sh. M. Salikhov; F. Z. Galin; M. G. Safarov; F. A. Valeev

doi:10.1134/S107042801605016X

Oxidation with CrO₃·2Py of levoglucosenone and 1,3-dienes Diels-Alder adducts

Authors: Biktagirov I.M.¹, Faizullina L.K.¹, Salikhov S.M.¹, Galin F.Z.¹, Safarov M.G.¹, Valeev F.A.¹
Affiliations:
1. Ufa Institute of Chemistry
Issue: Vol 52, No 5 (2016)
Pages: 711-720
Section: Article
URL: https://journal-vniispk.ru/1070-4280/article/view/214345
DOI: https://doi.org/10.1134/S107042801605016X
ID: 214345

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Abstract

Diels-Alder adducts of levoglucosenone with 1,3-butadiene, piperylene, and isoprene, and also some of their derivatives undergo allylic oxidation with CrО₃·2Py only in the case when the effect of a keto group or of another electron-acceptor group in the γ-position with respect to the double bond is removed.