Email this article Synthesis of fullerene C60 monoadducts. Cyclopropanation of C60 with sulfonium ylides
- Authors: Nikolaev D.N.1, Davidovich P.B.2, Piotrovskii L.B.1
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Affiliations:
- Institute of Experimental Medicine
- St. Petersburg State Institute of Technology
- Issue: Vol 52, No 7 (2016)
- Pages: 1050-1053
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/214761
- DOI: https://doi.org/10.1134/S107042801607023X
- ID: 214761
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Abstract
3′H-Cyclopropa[1,9](C60-Ih)[5,6]fullerene-3′-carboxylic acid can be synthesized in a good yield by cyclopropanation of fullerene C60 with 2-(dimethyl-λ4-sulfanylidene)acetates provided that the ester residue is readily hydrolyzable in acid medium.
About the authors
D. N. Nikolaev
Institute of Experimental Medicine
Author for correspondence.
Email: pp225@yandex.ru
Russian Federation, ul. Akad. Pavlova 12, St. Petersburg, 197376
P. B. Davidovich
St. Petersburg State Institute of Technology
Email: pp225@yandex.ru
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013
L. B. Piotrovskii
Institute of Experimental Medicine
Email: pp225@yandex.ru
Russian Federation, ul. Akad. Pavlova 12, St. Petersburg, 197376
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