Chemical transformations of tetracyclo[3.3.1.1.3,7.0.1,3]decane (1,3-dehydroadamantane): I. Reaction of 1,3-dehydroadamantane with carboxylic acids esters


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Abstract

Adamantylation of carboxylic acids esters was performed with 1,3-dehydroadamantane for the first time. The reaction proceeds under mild conditions and can be used as a convenient single stage procedure for the synthesis of esters of branched carboxylic acids having an adamantyl group in the α-position to the carbonyl group.

About the authors

V. M. Mokhov

Volgograd State Technical University

Email: butov@volpi.ru
Russian Federation, Volgograd

V. V. Burmistrov

Volzhskii Polytechnical Institute branch

Email: butov@volpi.ru
Russian Federation, ul. Engelsa 42A, Volzhskii, 404121

G. M. Butov

Volzhskii Polytechnical Institute branch

Author for correspondence.
Email: butov@volpi.ru
Russian Federation, ul. Engelsa 42A, Volzhskii, 404121

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