Email this article 1-Bromo-3,3,3-trifluoro-1-nitropropene: Synthesis and reaction with phenyl azide
- Authors: Anisimova N.A.1,2, Slobodchikova E.K.1, Kuzhaeva A.A.3, Stukan’ E.V.1, Bagryanskaya I.Y.4,5, Berestovitskaya V.M.1
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Affiliations:
- Herzen State Pedagogical University of Russia
- St. Petersburg State University of Industrial Technologies and Design
- St. Petersburg Mining University
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 52, No 10 (2016)
- Pages: 1379-1384
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/215007
- DOI: https://doi.org/10.1134/S1070428016100018
- ID: 215007
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Abstract
An improved procedure was developed for the synthesis of 3,3,3-trifluoro-1-nitropropene, and a new representative of gem-bromonitroalkenes, 1-bromo-3,3,3-trifluoro-1-nitropropene, was synthesized therefrom. Its reaction with phenyl azide gave a mixture of two regioisomeric 1,2,3-triazoles, from which pure 5-nitro-1-phenyl-4-(trifluoromethyl)-1H-1,2,3-triazole was isolated.
About the authors
N. A. Anisimova
Herzen State Pedagogical University of Russia; St. Petersburg State University of Industrial Technologies and Design
Author for correspondence.
Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186; ul. Bol’shaya Morskaya 18, St. Petersburg, 191186
E. K. Slobodchikova
Herzen State Pedagogical University of Russia
Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186
A. A. Kuzhaeva
St. Petersburg Mining University
Email: kohrgpu@yandex.ru
Russian Federation, 21 Liniya V.O. 2, St. Petersburg, 199106
E. V. Stukan’
Herzen State Pedagogical University of Russia
Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186
I. Yu. Bagryanskaya
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch; Novosibirsk State University
Email: kohrgpu@yandex.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
V. M. Berestovitskaya
Herzen State Pedagogical University of Russia
Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186
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