Email this article Synthesis of 1-organyl-1-(trimethylsiloxy)-2-(dimethylamino)ethenes and new hypervalent silicon compounds based thereon
- Authors: Gostevskii B.A.1, Albanov A.I.1, Vashchenko A.V.1, Smirnov V.I.1
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Affiliations:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Issue: Vol 52, No 10 (2016)
- Pages: 1385-1389
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/215008
- DOI: https://doi.org/10.1134/S107042801610002X
- ID: 215008
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Abstract
1-Organyl-1-(trimethylsiloxy)-2-(dimethylamino)ethenes were synthesized for the first time, and their reactions with trichloro(methyl)silane and trifluoro(phenyl)silane afforded silicon bis-chelates, methylbis-[2-(dimethylamino)-1-(organyl)ethenolato-N,O]siliconium chlorides and bis[1-(dimethylamino)-3,3-dimethylbut-1-en-2-olato-N,O]fluoro(phenyl)silicon(IV), respectively.
About the authors
B. A. Gostevskii
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Author for correspondence.
Email: gost_bgu@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
A. I. Albanov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: gost_bgu@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
A. V. Vashchenko
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: gost_bgu@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
V. I. Smirnov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: gost_bgu@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
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