Email this article Conversion of carbon dioxide to propionaldehyde over cobalt and rhodium nanoparticles supported on MIL-53 (Al) metal–organic framework
- Authors: Tarasov A.L.1, Isaeva V.I.1, Beletskaya I.P.1,2, Kustov L.M.1,2
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Affiliations:
- Zelinskii Institute of Organic Chemistry
- Faculty of Chemistry
- Issue: Vol 52, No 12 (2016)
- Pages: 1728-1732
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/215394
- DOI: https://doi.org/10.1134/S1070428016120022
- ID: 215394
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Abstract
The two-step conversion of carbon dioxide to propionic acid and propionaldehyde has been studied in the presence of novel catalysts, cobalt and rhodium nanoparticles supported on MIL-53(Al) microporous metal–organic framework. The first step is hydrogenation of carbon dioxide with formation of synthesis gas over cobalt-containing catalyst Co/MIL-53(Al) (500°C, 1 atm), and the second step is continuous (without separation) Rh/MIL-53 (Al)-catalyzed hydroformylation of ethylene with the synthesis gas formed in the first step.
About the authors
A. L. Tarasov
Zelinskii Institute of Organic Chemistry
Email: lmk@ioc.ac.ru
Russian Federation, Leninskii pr. 47, Moscow, 119991
V. I. Isaeva
Zelinskii Institute of Organic Chemistry
Author for correspondence.
Email: lmk@ioc.ac.ru
Russian Federation, Leninskii pr. 47, Moscow, 119991
I. P. Beletskaya
Zelinskii Institute of Organic Chemistry; Faculty of Chemistry
Email: lmk@ioc.ac.ru
Russian Federation, Leninskii pr. 47, Moscow, 119991; Leninskie gory 1, Moscow, 119991
L. M. Kustov
Zelinskii Institute of Organic Chemistry; Faculty of Chemistry
Email: lmk@ioc.ac.ru
Russian Federation, Leninskii pr. 47, Moscow, 119991; Leninskie gory 1, Moscow, 119991
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