Email this article Synthetic transformations of higher terpenoids: XXXVI. Synthesis of furanolabdanoid glycoconjugates with a 1,2,3-triazole linker
- Authors: Kremenko O.I.1, Kharitonov Y.V.1, Shul’ts E.E.1
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Affiliations:
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Issue: Vol 53, No 1 (2017)
- Pages: 35-46
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/215599
- DOI: https://doi.org/10.1134/S1070428017010079
- ID: 215599
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Abstract
Procedures have been developed for the synthesis of 16-[(propargyloxy)methyl]- and 7- and 18-(propargyloxy)labda-8(9),13,14-trienes from phlomisoic acid. Copper-catalyzed cycloaddition of the labdanoid alkynes to azido derivatives of α-D-glucose, D-galactose, D-xylose, and L-arabinose afforded the corresponding N-glycosyl-1,2,3-triazole conjugates.
About the authors
O. I. Kremenko
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: schultz@nioch.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
Yu. V. Kharitonov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: schultz@nioch.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
E. E. Shul’ts
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Author for correspondence.
Email: schultz@nioch.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
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