Reactions of caryophyllene oxide with ethane-1,2-dithiol and 2-sulfanylethanol catalyzed by Lewis acids


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Abstract

Reactions of caryophyllene oxide with ethane-1,2-dithiol and 2-sulfanylethanol in the presence of Lewis acids (BF3 · Et2O and ZnCl2) as catalyst afforded addition products with caryophyllane and clovane structures.

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Yu. V. Gyrdymova

Institute of Chemistry, Komi Scientific Center, Ural Branch

Author for correspondence.
Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982

S. A. Rubtsova

Institute of Chemistry, Komi Scientific Center, Ural Branch

Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982

A. V. Kutchin

Institute of Chemistry, Komi Scientific Center, Ural Branch

Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982

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