Email this article Formation of 1-aminophenazine from 3,4-dihydrophenazin-1(2H)-one oxime in the system acetylene–KOH–DMSO
- Authors: Petrova O.V.1, Sobenina L.N.1, Budaev A.B.1, Ivanov A.V.1, Samsonov V.A.2, Tikhonov A.Y.2, Trofimov B.A.1
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Affiliations:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Issue: Vol 53, No 1 (2017)
- Pages: 150-152
- Section: Short Communications
- URL: https://journal-vniispk.ru/1070-4280/article/view/215721
- DOI: https://doi.org/10.1134/S1070428017010316
- ID: 215721
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Abstract
The reaction of 3,4-dihydrophenazin-1(2H)-one oxime with acetylene in the superbasic system KOH–DMSO afforded 1-aminophenazine in 32% yield instead of the expected pyrrolophenazine. The same product was also obtained under analogous conditions in the absence of acetylene.
About the authors
O. V. Petrova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
L. N. Sobenina
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
A. B. Budaev
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
A. V. Ivanov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
V. A. Samsonov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
A. Ya. Tikhonov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
B. A. Trofimov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Author for correspondence.
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
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