Desilatranation of 1-organylsilatranes


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Abstract

Reaction of phenyltrifluorosilane with 1-hydro- and 1-ethoxysilatranes proceeds with the cleavage of the F–Si bond and the formation of 1-fluorosilatrane. Under the action of alkylsilatranes also the cleavage of C–Si bond is observed with the formation of a minor product, 1-fluorosilatrane.

About the authors

E. A. Grebneva

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: omtrof@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

Yu. I. Bolgova

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: omtrof@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

O. M. Trofimova

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Author for correspondence.
Email: omtrof@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

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