Differentiation of keto groups in the Michael adducts of levoglucosenone with cyclohexanone
- Autores: Galimova Y.S.1, Tagirov A.R.1, Faizullina L.K.1, Salikhov S.M.1, Valeev F.A.1
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Afiliações:
- Ufa Institute of Chemistry
- Edição: Volume 53, Nº 3 (2017)
- Páginas: 374-380
- Seção: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/215909
- DOI: https://doi.org/10.1134/S1070428017030113
- ID: 215909
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Resumo
The keto group in the carbohydrate residue of diastereoisomeric Michael adducts of levoglucosenone and cyclohexanone is more reactive than that in the cyclohexanone fragment. The adducts have been converted to the corresponding ethylene, trimethylene, and dimethyl ketals, tosylhydrazones, oxiranes, and Wittig methylenation products with complete or high regioselectivity.
Sobre autores
Yu. Galimova
Ufa Institute of Chemistry
Email: sinvmet@anrb.ru
Rússia, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
A. Tagirov
Ufa Institute of Chemistry
Email: sinvmet@anrb.ru
Rússia, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
L. Faizullina
Ufa Institute of Chemistry
Autor responsável pela correspondência
Email: sinvmet@anrb.ru
Rússia, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
Sh. Salikhov
Ufa Institute of Chemistry
Email: sinvmet@anrb.ru
Rússia, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
F. Valeev
Ufa Institute of Chemistry
Email: sinvmet@anrb.ru
Rússia, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
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