Reaction of phosphorylated 2,6-di-tert-butyl-4-methylenecyclohexa-2,5-dien-1-ones with 2,2′-[1,3-phenylenebis(oxy)]-di(ethan-1-amine)


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Abstract

Dialkyl [(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)methyl]phosphonates reacted with 2,2′-[1,3-phenylenebis(oxy)]di(ethan-1-amine) dihydrochloride at a ratio of 2: 1 in dioxane in the presence of potassium carbonate to give previously unknown tetraalkyl {1,3-phenylenebis[oxyethane-2,1-diylazanediyl-(3,5-di-tert-butyl-4-hydroxyphenylmethylene)]}bisphosphonates in high yields.

About the authors

E. M. Gibadullina

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Author for correspondence.
Email: elmirak@iopc.ru
Russian Federation, ul. Arbuzova 8, Kazan, Tatarstan, 420088

Nguyen Thi Thu

Kazan National Research Technological University

Email: elmirak@iopc.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015

R. R. Azmukhanova

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: elmirak@iopc.ru
Russian Federation, ul. Arbuzova 8, Kazan, Tatarstan, 420088

A. R. Burilov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: elmirak@iopc.ru
Russian Federation, ul. Arbuzova 8, Kazan, Tatarstan, 420088

M. A. Pudovik

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: elmirak@iopc.ru
Russian Federation, ul. Arbuzova 8, Kazan, Tatarstan, 420088

A. G. Strelnik

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: elmirak@iopc.ru
Russian Federation, ul. Arbuzova 8, Kazan, Tatarstan, 420088

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