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Synthesis of thiols from isobornylphenols


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Abstract

4-(3-Sulfanylpropyl)-2-isobornyl-6-methylphenol and 4-(sulfanylmethyl)-2,6-diisobornylphenol were synthesized from the corresponding 4-(bromoalkyl)phenols according to known procedures. Isobornylphenol with a trimethylene linker was converted into thiol by alkaline hydrolysis of thiouronium salt. The methylene-bridged analog was obtained by reduction of S-benzyl thioacetate with LiAlH4.

About the authors

I. Yu. Chukicheva

Institute of Chemistry, Komi Scientific Center, Ural Branch

Email: sukrusheva@mail.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982

O. V. Sukrusheva

Institute of Chemistry, Komi Scientific Center, Ural Branch

Author for correspondence.
Email: sukrusheva@mail.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982

A. V. Kutchin

Institute of Chemistry, Komi Scientific Center, Ural Branch

Email: sukrusheva@mail.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982

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