Halocyclization of products of allyl isothiocyanate addition to acyclic methylene active compounds


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Abstract

Products of allyl isothiocyanate addition to methylene active compounds, salt-like N-allyl-N,S-ketenacetals or N-allylthioamides, react with iodine, bromine or N-bromosuccinimide with the formation of derivatives of 2-ylidene-5-halomethylthiazolidines. A dependence was found of isomeric composition of obtained thiazolidines on the solvent nature.

About the authors

M. B. Litvinchuk

Lesya Ukrainka Eastern-European National University

Author for correspondence.
Email: mariia.litvinchuk@gmail.com
Ukraine, pr. Voli 13, Lutsk, 43025

A. V. Bentya

Institute of Organic Chemistry

Email: mariia.litvinchuk@gmail.com
Ukraine, Kiev

N. Yu. Slyvka

Lesya Ukrainka Eastern-European National University

Email: mariia.litvinchuk@gmail.com
Ukraine, pr. Voli 13, Lutsk, 43025

M. V. Vovk

Institute of Organic Chemistry

Email: mariia.litvinchuk@gmail.com
Ukraine, Kiev

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