Email this article Oxidative transformations of alkyl caryophyllanyl sulfides
- Authors: Gyrdymova Y.V.1, Sudarikov D.V.1, Rubtsova S.A.1, Kutchin A.V.1
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Affiliations:
- Institute of Chemistry, Komi Scientific Center, Ural Branch
- Issue: Vol 53, No 6 (2017)
- Pages: 853-859
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/216337
- DOI: https://doi.org/10.1134/S1070428017060070
- ID: 216337
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Abstract
Sesquiterpene sulfoxides and sulfones were synthesized in up to 56 and 74% yields, respectively. The oxidation of sulfides was accompanied by rearrangement of the epoxide fragment to allylic alcohol with subsequent oxidation. The isomerization of 4,5-epoxycaryophyllane-15-thiol afforded for the first time 4,11,11-trimethyl-8-(sulfanylmethyl)bicyclo[7.2.0]undec-3-en-5-ol in 40–45% yield.
About the authors
Yu. V. Gyrdymova
Institute of Chemistry, Komi Scientific Center, Ural Branch
Author for correspondence.
Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167000
D. V. Sudarikov
Institute of Chemistry, Komi Scientific Center, Ural Branch
Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167000
S. A. Rubtsova
Institute of Chemistry, Komi Scientific Center, Ural Branch
Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167000
A. V. Kutchin
Institute of Chemistry, Komi Scientific Center, Ural Branch
Email: gyrdymova-jw@chemi.komisc.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167000
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