Email this article Reaction of difluoromethyl pentafluorophenyl sulfoxide with nucleophiles
- Authors: Koshcheev B.V.1, Maksimov A.M.1, Platonov V.E.1, Shelkovnikov V.V.1
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Affiliations:
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Issue: Vol 53, No 7 (2017)
- Pages: 1012-1016
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/216524
- DOI: https://doi.org/10.1134/S1070428017070089
- ID: 216524
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Abstract
Reactions of 1-(difluoromethanesulfinyl)pentafluorobenzene with sodium methoxide, sodium phenoxide, potassium hydrosulfide, and methylamine resulted in substitution of fluorine atom in the 4-position (in the reaction with methylamine, also in the 2-position). Treatment of the title compound with sodium hydroxide afforded pentafluorobenzene due to cleavage of the Carom‒S bond.
About the authors
B. V. Koshcheev
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: platonov@nioch.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
A. M. Maksimov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: platonov@nioch.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
V. E. Platonov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Author for correspondence.
Email: platonov@nioch.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
V. V. Shelkovnikov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: platonov@nioch.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
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