Synthesis of polyfluoralkylated 1,3,2-dioxaphospholane and 1,3,2-dioxaphosphorinane oxides

N. K. Gusarova; S. I. Verkhoturova; S. N. Arbuzova; T. I. Kazantseva; A. I. Albanov; A. M. Nalibaeva; G. K. Bishimbaeva

doi:10.1134/S107042801711001X

Synthesis of polyfluoralkylated 1,3,2-dioxaphospholane and 1,3,2-dioxaphosphorinane oxides

Authors: Gusarova N.K.¹, Verkhoturova S.I.¹, Arbuzova S.N.¹, Kazantseva T.I.¹, Albanov A.I.¹, Nalibaeva A.M.², Bishimbaeva G.K.²
Affiliations:
1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
2. Institute of Fuel, Catalysis, and Electrochemistry
Issue: Vol 53, No 11 (2017)
Pages: 1623-1629
Section: Article
URL: https://journal-vniispk.ru/1070-4280/article/view/216892
DOI: https://doi.org/10.1134/S107042801711001X
ID: 216892

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Abstract

Polyfluoroalkyl dichlorophosphates easily react with 1,2- or 1,3-alkanediols in a system pyridine–diethyl ether and afford 2-polyfluoroalkoxy-1,3,2-dioxaphospholane oxides or 2-polyfluoroalkoxy-1,3,2-dioxaphosphorinane oxides. In similar conditions the reaction of methyl dichlorophosphate with 1,2- and 1,3-alkanediols proceeds less effectively.