Email this article Synthesis of diamantane via skeletal isomerization of hydrogenated cyclohepta-1,3,5-triene dimers in ionic liquid [Et3NH]+ [Al2Cl7]–
- Authors: Aminov R.I.1, Khusnutdinov R.I.1
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Affiliations:
- Institute of Petrochemistry and Catalysis
- Issue: Vol 53, No 12 (2017)
- Pages: 1881-1883
- Section: Short Communications
- URL: https://journal-vniispk.ru/1070-4280/article/view/217062
- DOI: https://doi.org/10.1134/S107042801712017X
- ID: 217062
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Abstract
Diamantane was synthesized in 91–97% yield by skeletal isomerization of a mixture of hydrogenated cyclohepta-1,3,5-triene dimers, pentacyclo[8.4.0.03,7.04,14.06,11]tetradecane and pentacyclo-[7.5.0.02,8.05,14.07,11]tetradecane, at a ratio of 3: 2 in the presence of ionic liquid [Et3NH]+ [Al2Cl7]–.
About the authors
R. I. Aminov
Institute of Petrochemistry and Catalysis
Author for correspondence.
Email: inklab4@gmail.com
Russian Federation, pr. Oktyabrya 141, Ufa, 450075 Bashkortostan
R. I. Khusnutdinov
Institute of Petrochemistry and Catalysis
Email: inklab4@gmail.com
Russian Federation, pr. Oktyabrya 141, Ufa, 450075 Bashkortostan
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