Formation of a Cluster H2V10O284– under the Action of Brønsted Acids and Its Catalytic Activity in Oxidation of Alkylbenzenes
- Authors: Ul’yanova M.I.1, Pervova M.G.1, Slepukhin P.A.1,2, Aksenova T.V.2, Pestov A.V.1,2
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Affiliations:
- Postovskii Institute of Organic Synthesis, Ural Branch
- Ural Federal University named after the First President of Russia B.N. Yeltsin
- Issue: Vol 54, No 5 (2018)
- Pages: 687-690
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/217730
- DOI: https://doi.org/10.1134/S1070428018050020
- ID: 217730
Cite item
Abstract
New method was developed for the preparation of vanadium cluster of the composition {Me2NH2}4* H2V10O28 from vanadyl(IV) acetylacetonate in the presence of 2-hydroxy-2-trifluoromethylchroman-4-one or its synthetic precursor, 2′-hydroxyacetophenone. The structure of the cluster was proved by X-ray diffraction (XRD) analysis. The cluster of decavanadate catalyzes oxidation of toluene and o-xylene creating promising situation for developing new catalytic materials.
About the authors
M. I. Ul’yanova
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pestov@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Academicheskaya 22/20, Yekaterinburg, 620137
M. G. Pervova
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pestov@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Academicheskaya 22/20, Yekaterinburg, 620137
P. A. Slepukhin
Postovskii Institute of Organic Synthesis, Ural Branch; Ural Federal University named after the First President of Russia B.N. Yeltsin
Email: pestov@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Academicheskaya 22/20, Yekaterinburg, 620137; Yekaterinburg, 620002
T. V. Aksenova
Ural Federal University named after the First President of Russia B.N. Yeltsin
Email: pestov@ios.uran.ru
Russian Federation, Yekaterinburg, 620002
A. V. Pestov
Postovskii Institute of Organic Synthesis, Ural Branch; Ural Federal University named after the First President of Russia B.N. Yeltsin
Author for correspondence.
Email: pestov@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Academicheskaya 22/20, Yekaterinburg, 620137; Yekaterinburg, 620002
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