Oxidation of Adamantane with H2O2–CF3COCF3 · 1.5 H2O in the Presence of VO(acac)2


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The system hydrogen peroxide–hexafluoroacetone sesquihydrate effectively oxidizes adamantane in the presence of VO(acac)2 to afford 64% of adamantan-1-ol in tert-butyl alcohol or 76% of adamantan-2-one in a mixture of acetic acid with pyridine.

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K. Kislitsina

Institute of Petrochemistry and Catalysis

编辑信件的主要联系方式.
Email: inklab4@gmail.com
俄罗斯联邦, pr. Oktyabrya 141, Ufa Bashkortostan, 450075

N. Shchadneva

Institute of Petrochemistry and Catalysis

Email: inklab4@gmail.com
俄罗斯联邦, pr. Oktyabrya 141, Ufa Bashkortostan, 450075

R. Khusnutdinov

Institute of Petrochemistry and Catalysis

Email: inklab4@gmail.com
俄罗斯联邦, pr. Oktyabrya 141, Ufa Bashkortostan, 450075

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