Nitration of 3-Methylaceperidazines with a Large Excess of Fuming Nitric Acid
- Autores: Omelichkin N.I.1, Minyaeva L.G.1, Milov A.A.2, Kuz’mina L.G.3, Mezheritskii V.V.1
-
Afiliações:
- Research Institute of Physical and Organic Chemistry
- Southern Scientific Center of the Russian Academy of Sciences
- Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
- Edição: Volume 54, Nº 8 (2018)
- Páginas: 1205-1212
- Seção: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/218619
- DOI: https://doi.org/10.1134/S1070428018080146
- ID: 218619
Citar
Resumo
Nitration of N-acetyl-3-methylaceperidazine with a 2–3-fold excess of nitric acid (d 1.36, 1.48) in glacial acetic acid results in the exclusive formation of mono- and dinitroderivatives. The nitration of 3-methylaceperidazine and its N-alkyl- and N-acetyl-substituted derivatives with a 6–9-fold excess of fuming nitric acid (d 1.54) in the same conditions results in the formation of both the expected products of mono- and dinitration and a product of the electrophilic addition of nitric acid to a double bond of acenaphthene scaffold of the molecule of nitration product.
Sobre autores
N. Omelichkin
Research Institute of Physical and Organic Chemistry
Autor responsável pela correspondência
Email: niomelichkin@sfedu.ru
Rússia, pr. Stachki 194/2, Rostov-on-Don, 344090
L. Minyaeva
Research Institute of Physical and Organic Chemistry
Email: niomelichkin@sfedu.ru
Rússia, pr. Stachki 194/2, Rostov-on-Don, 344090
A. Milov
Southern Scientific Center of the Russian Academy of Sciences
Email: niomelichkin@sfedu.ru
Rússia, Rostov-on-Don, 344006
L. Kuz’mina
Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: niomelichkin@sfedu.ru
Rússia, Moscow, 119991
V. Mezheritskii
Research Institute of Physical and Organic Chemistry
Email: niomelichkin@sfedu.ru
Rússia, pr. Stachki 194/2, Rostov-on-Don, 344090
Arquivos suplementares
