Email this article Nitrimines: VII. Reaction of S,S′-Dimethyl-N-nitroimidodithiocarbonate with Alkali. Synthesis of S-Methyl-N-nitrothiocarbamate and Its Salts
- Authors: Astakhov A.M.1, Antishin D.V.1, Nefedov А.А.2, Salnikov G.E.2, Buka E.S.1
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Affiliations:
- Reshetnev Siberian State University of Science and Technology
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Issue: Vol 54, No 11 (2018)
- Pages: 1638-1642
- Section: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/219364
- DOI: https://doi.org/10.1134/S1070428018110039
- ID: 219364
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Abstract
Reaction of S,S′-dimethyl-N-nitroimidodithiocarbonate with alkali in aqueous-alcoholic solution results in salts of S-methyl-N-nitrothiocarbamate. In anhydrous ethanol a salt of nitrouretane is obtained. By the reaction of S-methyl-N-nitrothiocarbamate salts with hydrazine 4-nitrosemicarbazide salts were prepared.
About the authors
A. M. Astakhov
Reshetnev Siberian State University of Science and Technology
Author for correspondence.
Email: alexastachov@mail.ru
Russian Federation, pr. im. gazety “Krasnoyarskii rabochii” 31, Krasnoyarsk, 660037
D. V. Antishin
Reshetnev Siberian State University of Science and Technology
Email: alexastachov@mail.ru
Russian Federation, pr. im. gazety “Krasnoyarskii rabochii” 31, Krasnoyarsk, 660037
А. А. Nefedov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: alexastachov@mail.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
G. E. Salnikov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: alexastachov@mail.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
E. S. Buka
Reshetnev Siberian State University of Science and Technology
Email: alexastachov@mail.ru
Russian Federation, pr. im. gazety “Krasnoyarskii rabochii” 31, Krasnoyarsk, 660037
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